Basic Pool Chemistry 101
- Matt Giovanisci
There are 2 basic elements to pool chemistry: water balance and sanitation.
1. Water Balance
Your pool water is delicate, and in order to reach perfect pool harmony, it must be balanced.
Balancing your pool means keeping the pH of the water between 7.4 and 7.6, which is slightly above neutral on the pH scale.
There are 3 main ingredients to keeping this balanced: pH, alkalinity and calcium hardness.
pH alone is unstable. Rainwater, swimmers, and just about anything that enters the water can affect the pH level. When pH is low, it means your water is acidic, and when it’s high, you water is basic.
To give you an idea of how pH works, our tears are pH neutral. If they had a low pH, it would burn when we cried. And if the pH was high, it would dry out our eyes.
Always keep a good supply of pH Increaser on hand because this reading can change frequently.
Alkalinity is a pH buffer, meaning it helps to keep the pH from drastically moving up and down the pH scale by absorbing major changes to the waters before affecting the pH.
It’s also a good idea to keep a hefty supply of alkalinity increaser on hand since this reading can fluctuate.
Without calcium, your water will become hungry for it and seek to fulfill it’s appetite by feasting on your pool’s plaster, and anywhere else it can get it.
Adding calcium hardness to your water will help protect your pool walls and equipment in the long run. However, too much calcium can cause scaling and other issues.
[NOTE: Calcium hardness should only be added once in the beginning of the season. Keep an eye on it throughout the year to make sure it stays within range. If the calcium in your water is high, you will have to dilute the water by draining it a tad and refill with fresh water.]
How To Keep Your Water Balanced
It’s important to keep your eye on your pH and alkalinity levels – at least once a week – by using a home test kit or test strips.
To keep your pool balanced, you need to keep these chemicals on hand:
You’ll notice I didn’t mention alkalinity decreaser. Most major pool chemical companies do not produce it and here’s why…
If your pH and alkalinity are low, alkalinity increaser will raise both. You may need to add a little pH increaser if the pH doesn’t reach 7.4 – like fine tuning an instrument.
If your pH and alkalinity are both high, pH decreaser will lower both.
If just your alkalinity is high, your pH will also be high and you can use pH decreaser.
If your pool is properly balanced at all times, it will make your pool’s sanitizer work more effectively – especially chlorine.
The most common form of pool sanitizer is chlorine, but there are others you can use, including:
- Bromine: chlorine’s halogen cousin
- Biguanide: Baquacil or SoftSwim
- Minerals: silver and copper
Chlorine is an extremely effective bacteria and algae killer, and cost effective.
There are a few ways you can introduce chlorine into the pool water, including:
- Chlorine tablets
- Chlorine granular or powdered chlorine
- Salt Chlorine Generator: turns regular table salt into chlorine
Chlorine tablets are the most popular form. They come in 3” and 1” tablets and can be added to a floating chlorine dispenser, a chlorinator, or the skimmer basket(s) in your pool.
[NOTE: When buying chlorine make sure you look for Trichloro or Dichloro as an active ingredient. These types of chlorine products are stabilized. UV rays from the sun eat up chlorine, but if it’s stabilized, it drastically slows down this process. We will talk more about chlorine stabilizer later.]
Bromine is chlorine’s halogen cousin and it more commonly used in hot tubs and indoor pools because it doesn’t give off that “chlorine” smell.
Bromine works a little differently than chlorine and it’s not as effective when dealing with certain types of algae. It’s not recommended for outdoor pools in direct sunlight. Sunlight eats up bromine very fast because it’s unstabilized.
This is a chlorine alternative. It’s an effective sanitizer for swimming pools and even makes the water feel smoother.
Sanitizers like Baquacil and SoftSwim are part of a total chemical package and should not be mixed with standard pool chemicals. You must stick the pool chemicals offered by these brands, including shock and algaecide.
These chemical packages are more expensive than traditional chlorine-compatible chemicals, and they come in liquid form.
Silver and copper minerals are introduced to the water by an ionizer that resembles a chlorinator. These minerals work to sanitize the water, but they are much slower than chlorine.
A mineral system is NOT a complete chlorine alternative as chlorine is still required – but only a small amount as backup.
When a chlorine particle attacks and kills bacteria, or other organic material in your water, it forms a chloramine, which is chlorine that doesn’t kill anymore. This particle just floats around in your water until it can be oxidized and broken apart.
In order to oxidize these chloramines, you must “shock” the water by adding enough chlorine – or non-chlorine shock including Potassium Monopersulfate – to reach breakpoint oxidation.
I personally recommend using calcium hypochlorite pool shock at least once a week.
What is Breakpoint Oxidation?
To reach breakpoint oxidation, the chlorine reading must be 10 ppm over your combined chlorine reading.
Your chlorine has two readings: free chlorine (FC) and combined chlorine (CC). Free chlorine refers to the chlorine that is free and available to kill. Combined chlorine is those chloramines we talked about.
NOTE: Pool shock products are made with unstabilized chlorine or no chlorine at all. They will go in, do their job, and get eaten up by the sun’s UV rays very fast. That’s why it’s important to shock your pool at night or dusk, and let it work for 8 hours (with the pool running) throughout the night.
How to Shock a Swimming Pool
Want to learn how to shock a pool? Watch this video and follow along with these easy steps to successfully shock your swimming pool.
Click here to learn more »
You should shock or oxidize your pool at least once a week.
Other Types of Pool Chemicals You Need To Know About
If you only used pH, alkalinity, calcium, and a sanitizer, you could keep a clean and healthy pool all year long. However, there are a few more products you should be familiar with in case you need or decide to use them.
Cyanuric Acid (Water Stabilizer)
Most chlorine products you add to the water will be stabilized chlorine. However, if you start with fresh water, you might want to add some cyanuric acid (aka water stabilizer) as a stabilizer base so that the chlorine doesn’t get burned off by the sun’s UV rays so quickly. This chemical will protect your chlorine from the sun.
Use algaecide as a backup. If your chlorine levels dip down, and you don’t catch it in time, the algaecide will keep the algae at bay until you can get the chlorine back up.
If you’re currently having an algae problem in your pool, algaecide may not be your best option. Thankfully, we have a solution to help you get rid of algae and keep it from coming back in the following article:
How to Get Rid of Pool Algae
Having trouble with pool algae? If so, it's very easy to get rid of. Just follow these steps to kill pool algae and stop it from coming back!
Click here to learn more »
Clarifier and Floc
A water clarifier helps by bringing all those tiny particles that are making your water cloudy and combining them into bigger particles that your filter will have a better chance of filtering out.
Floc or Flocculant, grabs those tiny particles, brings them together, and sinks them to the bottom. With pool floc, you will have to manually get those particles out of your water by vacuuming to waste.
How to Fix Cloudy Pool Water
Got cloudy pool water? We'll teach you a few methods on how to clear your cloudy swimming pool as quickly as possible.
Click here to learn more »
Stain and Scale Remover (Metal Remover)
If you have metals in your water, like copper and iron, you can use a metal remover or stain and scale remover to keep those metals in solution so that your filter can filter them out.
If metals come out of solution that can attach themselves to the walls and other parts of your pool and produce unsightly stains.
How to Identify and Remove Pool Stains
To address this problem, the source of pool stains must be identified, and the appropriate solution introduced as soon as possible. Follow along here.
Click here to learn more »
To maintain a safe and healthy swimming pool, you need to keep your pool chemicals at the following levels:
- pH: 7.4 to 7.6
- Alkalinity: 100 to 150 ppm
- Calcium Hardness: 175 to 225 ppm and 225 to 275 ppm for plaster pools
- For Chlorine or Salt Water Pools: 1 to 3 ppm (I recommend you keep it at 3 ppm)
- For Bromine Pools: 3 to 5 ppm
- For Biguanide Pools: 30 to 50 ppm
- For Mineral System Pools: 0.5 ppm of chlorine
Make sure to practice good pool circulation and filtering, and keep your pool cleaned by vacuuming and skimming frequently.
My 3 Cs of pool care include: cleaning, circulation and chemicals. I suggest you read these posts to understand how to keep your pool clean and healthy all season long:
- How to Keep Your Pool Clean
- The Importance of Swimming Pool Circulation
- The Anatomy of a Swimming Pool
I added The Anatomy of a Swimming Pool because you should know what you’re working with before you get started.
(Photo Credits: Zodiac Pool Systems, Pool Supply World)